IndiumV3, Main, Repository, bibRecord, 013317

Electrochemical and 119Sn Mössbauer study of sulfospinels as anode materials for lithium-ion batteries

Identifieur interne : 013317 ( Main/Repository ); précédent : 013316; suivant : 013318

Electrochemical and 119Sn Mössbauer study of sulfospinels as anode materials for lithium-ion batteries

Auteurs : RBID : Pascal:01-0065974

Descripteurs français

Pascal (Inist)
- Batterie, Accumulateur électrochimique, Insertion, Lithium Ion, Matériau électrode, Spinelles, Cuivre Sulfure, Indium Sulfure, Etain Sulfure, Mécanisme réaction, Spectrométrie Mössbauer, Etain 119, Caractéristique électrique, Cycle charge décharge, Diffraction RX, CuInSnS4, Cu In S Sn, Cu0,73In1,82Sn0,45S4.

English descriptors

KwdEn :
- Battery, Copper Sulfides, Discharge charge cycle, Electrical characteristic, Electrode material, Indium Sulfides, Insertion, Lithium Ions, Moessbauer spectrometry, Reaction mechanism, Secondary cell, Spinels, Tin 119, Tin Sulfides, X ray diffraction.

Abstract

119Sn Mössbauer spectroscopy, X-ray diffraction and electrochemical experiments were carried out to characterize the reaction mechanism of lithium with spinel phases of the Cu₂S In₂S₃-SnS₂ system. This analysis reveals an irreversible part of the mechanism linked to the reduction of the cations involving a spinel to rocksalt transformation followed by a structural breakdown, and a reversible part linked to the formation of lithium-metal alloys. The electrochemical investigation has shown interesting reversible capacities for these materials and their possible use as anode materials in lithium-ion cells.

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Pascal:01-0065974

Le document en format XML

<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en" level="a">Electrochemical and <sup>119</sup>
Sn Mössbauer study of sulfospinels as anode materials for lithium-ion batteries</title>
<author><name sortKey="Dedryvere, R" uniqKey="Dedryvere R">R. Dedryvere</name>
<affiliation wicri:level="4"><inist:fA14 i1="01"><s1>Laboratoire des Agrégats Moléculaires et Matériaux Inorganiques (UMR 5072 CNRS), Université Montpellier II, CC15, Place Eugène Bataillon</s1>
<s2>34095 Montpellier</s2>
<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
</inist:fA14>
<country>France</country>
<placeName><region type="region" nuts="2">Languedoc-Roussillon</region>
<settlement type="city">Montpellier</settlement>
</placeName>
<orgName type="university">Université Montpellier 2</orgName>
</affiliation>
</author>
<author><name sortKey="Olivier Fourcade, J" uniqKey="Olivier Fourcade J">J. Olivier-Fourcade</name>
<affiliation wicri:level="4"><inist:fA14 i1="01"><s1>Laboratoire des Agrégats Moléculaires et Matériaux Inorganiques (UMR 5072 CNRS), Université Montpellier II, CC15, Place Eugène Bataillon</s1>
<s2>34095 Montpellier</s2>
<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
</inist:fA14>
<country>France</country>
<placeName><region type="region" nuts="2">Languedoc-Roussillon</region>
<settlement type="city">Montpellier</settlement>
</placeName>
<orgName type="university">Université Montpellier 2</orgName>
</affiliation>
</author>
<author><name sortKey="Jumas, J C" uniqKey="Jumas J">J. C. Jumas</name>
<affiliation wicri:level="4"><inist:fA14 i1="01"><s1>Laboratoire des Agrégats Moléculaires et Matériaux Inorganiques (UMR 5072 CNRS), Université Montpellier II, CC15, Place Eugène Bataillon</s1>
<s2>34095 Montpellier</s2>
<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
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<country>France</country>
<placeName><region type="region" nuts="2">Languedoc-Roussillon</region>
<settlement type="city">Montpellier</settlement>
</placeName>
<orgName type="university">Université Montpellier 2</orgName>
</affiliation>
</author>
<author><name sortKey="Denis, S" uniqKey="Denis S">S. Denis</name>
<affiliation wicri:level="3"><inist:fA14 i1="02"><s1>Laboratoire de Réactivité et Chimie des Solides (UPRES-A 6007 CNRS), 33, rue Saint-Leu</s1>
<s2>80039 Amiens</s2>
<s3>FRA</s3>
<sZ>4 aut.</sZ>
</inist:fA14>
<country>France</country>
<placeName><region type="region" nuts="2">Picardie</region>
<settlement type="city">Amiens</settlement>
</placeName>
</affiliation>
</author>
<author><name sortKey="Lavela, P" uniqKey="Lavela P">P. Lavela</name>
<affiliation wicri:level="2"><inist:fA14 i1="03"><s1>Laboratorio de Química Inorgánica, Facultad de Ciencias, Universidad de Córdoba, Avda. San Alberto Magno s/n.</s1>
<s2>14004 Cordoba</s2>
<s3>ESP</s3>
<sZ>5 aut.</sZ>
<sZ>6 aut.</sZ>
</inist:fA14>
<country>Espagne</country>
<placeName><region nuts="2" type="communauté">Andalousie</region>
</placeName>
</affiliation>
</author>
<author><name sortKey="Tirado, J L" uniqKey="Tirado J">J. L. Tirado</name>
<affiliation wicri:level="2"><inist:fA14 i1="03"><s1>Laboratorio de Química Inorgánica, Facultad de Ciencias, Universidad de Córdoba, Avda. San Alberto Magno s/n.</s1>
<s2>14004 Cordoba</s2>
<s3>ESP</s3>
<sZ>5 aut.</sZ>
<sZ>6 aut.</sZ>
</inist:fA14>
<country>Espagne</country>
<placeName><region nuts="2" type="communauté">Andalousie</region>
</placeName>
</affiliation>
</author>
</titleStmt>
<publicationStmt><idno type="inist">01-0065974</idno>
<date when="2000">2000</date>
<idno type="stanalyst">PASCAL 01-0065974 INIST</idno>
<idno type="RBID">Pascal:01-0065974</idno>
<idno type="wicri:Area/Main/Corpus">011C97</idno>
<idno type="wicri:Area/Main/Repository">013317</idno>
</publicationStmt>
<seriesStmt><idno type="ISSN">0013-4686</idno>
<title level="j" type="abbreviated">Electrochim. acta</title>
<title level="j" type="main">Electrochimica acta</title>
</seriesStmt>
</fileDesc>
<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Battery</term>
<term>Copper Sulfides</term>
<term>Discharge charge cycle</term>
<term>Electrical characteristic</term>
<term>Electrode material</term>
<term>Indium Sulfides</term>
<term>Insertion</term>
<term>Lithium Ions</term>
<term>Moessbauer spectrometry</term>
<term>Reaction mechanism</term>
<term>Secondary cell</term>
<term>Spinels</term>
<term>Tin 119</term>
<term>Tin Sulfides</term>
<term>X ray diffraction</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Batterie</term>
<term>Accumulateur électrochimique</term>
<term>Insertion</term>
<term>Lithium Ion</term>
<term>Matériau électrode</term>
<term>Spinelles</term>
<term>Cuivre Sulfure</term>
<term>Indium Sulfure</term>
<term>Etain Sulfure</term>
<term>Mécanisme réaction</term>
<term>Spectrométrie Mössbauer</term>
<term>Etain 119</term>
<term>Caractéristique électrique</term>
<term>Cycle charge décharge</term>
<term>Diffraction RX</term>
<term>CuInSnS4</term>
<term>Cu In S Sn</term>
<term>Cu0,73In1,82Sn0,45S4</term>
</keywords>
</textClass>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en">119Sn Mössbauer spectroscopy, X-ray diffraction and electrochemical experiments were carried out to characterize the reaction mechanism of lithium with spinel phases of the Cu<sub>2</sub>
S In<sub>2</sub>
S<sub>3</sub>
-SnS<sub>2</sub>
 system. This analysis reveals an irreversible part of the mechanism linked to the reduction of the cations involving a spinel to rocksalt transformation followed by a structural breakdown, and a reversible part linked to the formation of lithium-metal alloys. The electrochemical investigation has shown interesting reversible capacities for these materials and their possible use as anode materials in lithium-ion cells.</div>
</front>
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Sn Mössbauer study of sulfospinels as anode materials for lithium-ion batteries</s1>
</fA08>
<fA11 i1="01" i2="1"><s1>DEDRYVERE (R.)</s1>
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<fA11 i1="02" i2="1"><s1>OLIVIER-FOURCADE (J.)</s1>
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<fA11 i1="03" i2="1"><s1>JUMAS (J. C.)</s1>
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<fA11 i1="06" i2="1"><s1>TIRADO (J. L.)</s1>
</fA11>
<fA14 i1="01"><s1>Laboratoire des Agrégats Moléculaires et Matériaux Inorganiques (UMR 5072 CNRS), Université Montpellier II, CC15, Place Eugène Bataillon</s1>
<s2>34095 Montpellier</s2>
<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
</fA14>
<fA14 i1="02"><s1>Laboratoire de Réactivité et Chimie des Solides (UPRES-A 6007 CNRS), 33, rue Saint-Leu</s1>
<s2>80039 Amiens</s2>
<s3>FRA</s3>
<sZ>4 aut.</sZ>
</fA14>
<fA14 i1="03"><s1>Laboratorio de Química Inorgánica, Facultad de Ciencias, Universidad de Córdoba, Avda. San Alberto Magno s/n.</s1>
<s2>14004 Cordoba</s2>
<s3>ESP</s3>
<sZ>5 aut.</sZ>
<sZ>6 aut.</sZ>
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<fA66 i1="01"><s0>GBR</s0>
</fA66>
<fC01 i1="01" l="ENG"><s0>119Sn Mössbauer spectroscopy, X-ray diffraction and electrochemical experiments were carried out to characterize the reaction mechanism of lithium with spinel phases of the Cu<sub>2</sub>
S In<sub>2</sub>
S<sub>3</sub>
-SnS<sub>2</sub>
 system. This analysis reveals an irreversible part of the mechanism linked to the reduction of the cations involving a spinel to rocksalt transformation followed by a structural breakdown, and a reversible part linked to the formation of lithium-metal alloys. The electrochemical investigation has shown interesting reversible capacities for these materials and their possible use as anode materials in lithium-ion cells.</s0>
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<s5>02</s5>
</fC03>
<fC03 i1="03" i2="X" l="FRE"><s0>Insertion</s0>
<s5>03</s5>
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<s5>03</s5>
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<fC03 i1="04" i2="X" l="ENG"><s0>Lithium Ions</s0>
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<fC03 i1="04" i2="X" l="SPA"><s0>Litio Ión</s0>
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<fC03 i1="08" i2="X" l="FRE"><s0>Indium Sulfure</s0>
<s2>NC</s2>
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<s5>08</s5>
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<fC03 i1="08" i2="X" l="ENG"><s0>Indium Sulfides</s0>
<s2>NC</s2>
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<fC03 i1="08" i2="X" l="SPA"><s0>Indio Sulfuro</s0>
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<s2>NA</s2>
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<fC03 i1="09" i2="X" l="FRE"><s0>Etain Sulfure</s0>
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<s2>NA</s2>
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<s2>NA</s2>
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<s2>FX</s2>
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<s5>10</s5>
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<s5>10</s5>
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<s5>11</s5>
</fC03>
<fC03 i1="11" i2="X" l="ENG"><s0>Moessbauer spectrometry</s0>
<s5>11</s5>
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<s5>11</s5>
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<fC03 i1="14" i2="X" l="ENG"><s0>Discharge charge cycle</s0>
<s5>17</s5>
</fC03>
<fC03 i1="14" i2="X" l="SPA"><s0>Ciclo carga descarga</s0>
<s5>17</s5>
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<s5>18</s5>
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<s5>18</s5>
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<fC03 i1="15" i2="X" l="SPA"><s0>Difracción RX</s0>
<s5>18</s5>
</fC03>
<fC03 i1="16" i2="X" l="FRE"><s0>CuInSnS4</s0>
<s4>INC</s4>
<s5>62</s5>
</fC03>
<fC03 i1="17" i2="X" l="FRE"><s0>Cu In S Sn</s0>
<s4>INC</s4>
<s5>63</s5>
</fC03>
<fC03 i1="18" i2="X" l="FRE"><s0>Cu0,73In1,82Sn0,45S4</s0>
<s4>INC</s4>
<s5>64</s5>
</fC03>
<fN21><s1>043</s1>
</fN21>
</pA>
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Electrochemical and 119Sn Mössbauer study of sulfospinels as anode materials for lithium-ion batteries

Electrochemical and 119Sn Mössbauer study of sulfospinels as anode materials for lithium-ion batteries

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English descriptors

Abstract

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